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15 million. 60) Application: To produce cumene from benzene and any grade of propylene—including lower-quality refinery propylene-propane mixture—using the Mobil/Badger process and a new generation of zeolite catalysts from ExxonMobil. The utilities can be optimized for specific site conditions/economics and integrated with an associated phenol plant. Description: The process include: a fixed-bed alkylation reactor, a fixed-bed transalkylation reactor and a distillation section. Liquid propylene and benzene are premixed and fed to the alkylation reactor (1), where propylene is completely reacted.
Reduced chilling train refrigeration requirements in the dephlegmator, 2. simultaneous chilling/prefractionation in the dephlegmator, 3. reduced methane content in feed to demethanizer, 4. partial deethanizer bypassing, 5. dual feed ethylene fractionator (lower reflux ratio) and 6. reduced refrigeration demand (approx. 75%). Economics: Ethylene yields range from 57% (ethane, high conversion) to 28% (heavy hydrogenated gas oils). Corresponding specific energy consumptions range from 3,000 kcal/kg to 6,000 kcal/kg.
Yields: Greater than 98% on raw materials. 19 Steam, t 5 Water, cooling , m3 300 Electricity, kWh 30 Commercial plants: One 20,000-mtpa original capacity facility. Licensor: Kvaerner Process Technology, UK. Copyright © 2001 by Gulf Publishing Company. All rights reserved. PETROCHEMICAL PROCESSES 2001 Dehydrogenation Ethanol feed 1 Refining 2 3 Hydrogen 3 Selective hydrogenation Recycle ethanol Ethyl acetate product Ethyl acetate Application: To produce ethyl acetate from ethanol without acetic acid or other co-feeds.