By Nathan Rotenstreich
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Griffiths, and D. H. Jones, Analyst 77, 897 (1952). A. T. James and A. J. P. Martin, Biochem. J. 50, 679–690 (1952). E. Glueckauf, in Ion Exchange and Its Applications, Society of the Chemical Industry, London, 1955, pp. 34–36. J. J. van Deemter, F. J. Zuiderweg, and A. Klinkenberg, Chem. Eng. Sci. 5, 271–289 (1956). M. J. E. Golay, in Gas Chromatography, V. J. Coates, H. J. Noebels, and I. S. , Academic Press, New York, 1958, pp. 1–13. J. C. Giddings, Dynamics of Chromatography, Part I, Principles and Theory, Marcel Dekker, New York, 1965, pp.
3 Integral-type chromatogram from frontal analysis. Component A is the least sorbed of four components. 6). This results in the peaks having sharp fronts and well-formed steps. 3 reflects the problem of analytical frontal analysis—it is difficult to calculate initial concentrations in the sample. One can, however, determine the number of components present in the sample. If the isotherms are linear, the zones may be diffuse. This may be caused by three important processes: inhomogeneity of the packing, large diffusion effects, and nonattainment of sorption equilibrium.
Geol. 23A(1) (1946). A. J. P. Martin, Biochem. Soc. Symp. 3, 4–15 (1949). E. Cremer and F. Prior, Z. Elektrochem. 55, 66 (1951); E. Cremer and R. Muller, Z. Elektrochem. 55, 217 (1951). C. S. G. Phillips, J. Griffiths, and D. H. Jones, Analyst 77, 897 (1952). A. T. James and A. J. P. Martin, Biochem. J. 50, 679–690 (1952). E. Glueckauf, in Ion Exchange and Its Applications, Society of the Chemical Industry, London, 1955, pp. 34–36. J. J. van Deemter, F. J. Zuiderweg, and A. Klinkenberg, Chem. Eng.